Development of a Generic Mechanism for the Dehydrocoupling of Amine-Boranes: A Stoichiometric, Catalytic, and Kinetic Study of H3B·NMe2H Using the [Rh(PCy3)2]+ Fragment
The multistage Rh-catalyzed dehydrocoupling of the secondary amine-borane H3B•NMe2H, to give the cyclic amino-borane [H2BNMe2]2, has been explored using catalysts based upon cationic [Rh(PCy3)2]+ (Cy = cyclo-C6H11)
Unit Operation: Reaction
Objective: Kinetics
Company: University of Bristol
Source: J. Am. Chem. Soc., 2012, 134 (7), pp 3598–3610
Authors: Guy C. Lloyd-Jones (University of Bristol), Laura J. Sewell (University of Bristol), Andrew S. Weller (University of Bristol)
Publish Date: 19-Jan-2012
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