Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism
The scope and mechanism of thermodynamically leveraged ester RC(O)O–R′ bond hydrogenolysis by tandem metal triflate + supported Pd catalysts are investigated both experimentally and theoretically by DFT and energy span analysis.
Unit Operation: Hydrogenation
Objective: Modeling
Company: Argonne National Laboratory, Northwestern University
Source: Energy Environ. Sci., 2016,9, 550-564
Authors: Rajeev S. Assary (Northwestern University), Larry A. Curtiss (Argonne National Laboratory), Zhi Li (Northwestern University), Tracy L. Lohr (Northwestern University), Tobin J. Marks (Northwestern University)
Publish Date: 26-Nov-2015
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